麻砂泥田与鳝泥田土壤团聚体分布特征及其对镉吸附与形态的影响
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贺汝婧(2000-),女,硕士研究生,主要从事环境土壤研究。E-mail:577130923@qq.com

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X53

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国家重点研发计划项目(2022YFD1700101)


Distribution Characteristics of Aggregates in Granitic Sandy Soil and Eel Clayey Soil and Their Effects on Cadmium Adsorption and Speciation
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    摘要:

    [目的] 为揭示土壤各粒级团聚体组分理化性质及其对镉(Cd)赋存形态的影响机制,研究典型水稻土团聚体分布特征及不同粒径团聚体对Cd环境行为的影响。[方法] 选取Cd污染水稻土麻砂泥田(花岗岩发育)与鳝泥田(板页岩发育),通过湿筛法将土壤团聚体分为4个粒级:大团聚体(2~8 mm)、中间团聚体(0.25~2 mm)、微团聚体(0.053~0.25 mm)和粉黏粒(<0.053 mm),分析不同粒径团聚体去除有机质与游离态氧化铁对Cd的吸附作用。[结果] 2种土壤均以大团聚体为主,鳝泥田团聚体结构较麻砂泥田稳定,其平均重量直径(MWD)和几何平均直径(GMD)均高于麻砂泥田。麻砂泥田中间团聚体占比较高,结构疏松,稳定性差,主要受母质中有机质和游离氧化铁质量分数偏低影响。随着粒径减小,团聚体有机质、游离氧化铁及阳离子交换量均显著升高。团聚体对外源Cd吸附能力均随粒径减小而增强,粉黏粒对Cd的吸附能力最强;去除有机质后团聚体对Cd吸附能力显著下降,而去除游离氧化铁后下降幅度较小。[结论] 不同土壤类型引起的团聚体组分和结构稳定性差异,将显著影响其对Cd的吸附及赋存形态,所得结果为揭示稻田重金属污染演变规律及制定修复策略提供科学依据。

    Abstract:

    [Objective] To reveal the physicochemical properties of soil aggregates at different particle sizes and their influence mechanisms on cadmium(Cd)speciation,this study investigates the distribution characteristics of aggregates in typical paddy soils and the effects of aggregates with different particle sizes on Cd environmental behavior. [Methods] Two types of Cd-contaminated paddy soils were selected,namely granitic sandy soil(developed from granite)and eel clayey soil(developed from shale and slate). Soil aggregates were separated into four size fractions using the wet-sieving method: macroaggregates (2-8 mm) , intermediate aggregates (0.25-2 mm) , micro-aggregates(0.053-0.25 mm),and silt-clay particles(<0.053 mm). The effects of removing organic matter and free iron oxides from aggregates of different sizes on Cd adsorption were analyzed. [Results] Both soils were dominated by macroaggregates. The eel clayey soil exhibited a more stable aggregate structure than the granitic sandy soil,with higher mean weight diameter(MWD)and geometric mean diameter(GMD). The granitic sandy soil had a higher proportion of small particle size aggregates with a looser structure and lower stability,mainly due to the lower mass fractions of organic matter and free iron oxides in its parent material. As aggregate size decreased,the organic matter,free iron oxide,and cation exchange capacity(CEC)of aggregates significantly increased. The adsorption capacity of all aggregates for exogenous Cd was enhanced with decreasing aggregate size,with the silt-clay particles demonstrating the strongest adsorption capacity. After the removal of organic matter,the Cd adsorption capacity significantly decreased,while the decrease after the removal of free iron oxides was relatively small. [Conclusion] The differences in aggregate composition and structural stability caused by different soil types significantly influence their Cd adsorption and speciation. These findings provide a scientific basis for understanding the evolution of heavy metal pollution in paddy fields and formulating remediation strategies.

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贺汝婧, 龙坚, 范海津, 肖子曼, 张坤, 侯颖珊, 侯红波, 彭佩钦.麻砂泥田与鳝泥田土壤团聚体分布特征及其对镉吸附与形态的影响[J].水土保持学报,2025,39(5):105~115

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  • 收稿日期:2025-03-06
  • 最后修改日期:2025-04-04
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  • 在线发布日期: 2025-10-20
  • 出版日期: 2025-10-28
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